Let be a Schrödinger operator acting on , where the nonnegative potential belongs to the reverse Hölder class for some . This article is primarily concerned with the study of endpoint boundedness for classical singular integral operators in the context of the space , consisting of functions of vanishing mean oscillation associated with . We establish the following main results: (i) the standard Hardy–Littlewood maximal operator is bounded on ; (ii) for each , the adjoint of the Riesz transform is bounded from into ; and (iii) the approximation to the identity generated by the Poisson and heat semigroups associated with characterizes appropriately. These results recover the classical analogues corresponding to the Laplacian as a special case. However, the presence of the potential introduces substantial analytical challenges, necessitating tools beyond the scope of classical Calderón–Zygmund theory. Our approach leverages precise heat kernel estimates and the structural properties of established by Song and the third author in [J. Geom. Anal. 32 (2022), no. 4, Paper No. 130, 37 pp].

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