We characterize the relationship between the size of the bright ring observed in simulated black hole images and the size of the analytic black hole shadow. Calibrating this relationship is crucial for mass measurements and, when independent mass measurements are available, for tests of general relativity using Event Horizon Telescope (EHT) images. We perform this calibration using a large set of high-resolution simulated images generated with different accretion-flow modeling approaches and spanning a wide range of system parameters and initial conditions. We show that the theoretical uncertainty in this relationship can be reduced significantly through future observations, improved imaging techniques, and the application of astrophysical or model-based constraints. In particular, the uncertainty decreases compared to existing measurements when (i) observing at 345 GHz, (ii) applying geometric image constraints, such as the ring width inference from the PRIMO image reconstruction algorithm, (iii) incorporating astrophysical constraints such as the black hole spin axis in M87 being aligned (or anti-aligned) with the large-scale jet observed at longer radio wavelengths, and (iv) assuming that the accretion flow can be described by a magnetically arrested field configuration. Finally, we quantify how the uncertainty is expected to decrease as additional observations are obtained in subsequent years and identify dwell-time filtering, i.e., evaluating the persistence of a geometric measurement over time, as a promising avenue for improving the precision of the calibration.

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