The spectrum is investigated using proton-proton collisions at a center-of-mass energy of 13TeV, corresponding to an integrated luminosity of 5.4fb, collected by the LHCb experiment during 2016–2018. Four states are observed with high significance, and their masses and widths are measured to be \begin{align*} m[Ξ_c(2815)^{+}] &= 2816.65 \pm 0.03 \pm 0.03 \pm 0.23 ~, Γ[Ξ_c(2815)^{+}] &= 2.07 \pm 0.08 \pm 0.12~,\[5pt] m[Ξ_c(2923)^{+}] &= 2922.8 \pm 0.3 \pm 0.5 \pm 0.2~, Γ[Ξ_c(2923)^{+}] &= 5.3 \pm 0.9 \pm 1.4~,\[5pt] m[Ξ_c(2970)^{+}] &= 2968.6 \pm 0.5 \pm 0.5 \pm 0.2~, Γ[Ξ_c(2970)^{+}] &= 31.7 \pm 1.7 \pm 1.9~,\[5pt] m[Ξ_c(3080)^{+}] &= 3076.8 \pm 0.7 \pm 1.3 \pm 0.2~, Γ[Ξ_c(3080)^{+}] &= 6.8 \pm 2.3 \pm 0.9~, \end{align*} where the uncertainties are statistical, systematic, and due to the limited precision on the mass, respectively. The baryon is observed for the first time, and is consistent with being the isospin partner of the previously observed state. Most of the measured parameters are more precise than existing world averages.

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