The muon collider has recently received a great deal of attention because of its ability to achieve both high energy and high luminosity. It plays as a gauge boson collider because the vector boson scattering (VBS) becomes the dominant production topology for Standard Model processes starting from a few TeV of collision energy. In this paper, we propose that the process of annihilation into tri-photon is also very sensitive to the search of anomalous quartic gauge couplings (aQGCs). We investigate the projected constraints on the transverse operators contributing to aQGCs through at muon colliders. For the muon collider with TeV and , the expected constraints are about two orders of magnitude stronger than those at the 13 TeV LHC.

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