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While key attention in transition-metal oxides is usually devoted to the states of the transition-metal ion, the O states usually also carry important physics. We here examine these states in representatives of the novel superconducting nickelates, as described in realistic dynamical mean-field theory. Since the materials are located on the boundary between Mott-Hubbard and charge-transfer systems, the role of oxygen is expectedly subtle. Strong reduction of doped holes on oxygen and first asymmetry effects are featured in infinite-layer nickelates. A pronounced nature of bridging orbitals is identified in the LaNiO system.

生成讲解博客的中文版本

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