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We show that a large class of non-degenerate second-order (maximally) superintegrable systems gives rise to Hessian structures, which admit natural (Hessian) coordinates adapted to the superintegrable system. In particular, abundant superintegrable systems on Riemannian manifolds of constant sectional curvature fall into this class. We explicitly compute the natural Hessian coordinates for examples of non-degenerate second-order superintegrable systems in dimensions two and three.

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