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Along the line of singular value estimates for commutators by Rochberg-Semmes, Lord-McDonald-Sukochev-Zanin and Fan-Lacey-Li, we establish the endpoint weak Schatten class estimate for commutators of Riesz transforms with multiplication operator on Heisenberg groups via homogeneous Sobolev norm of the symbol . The new tool we exploit is the construction of a singular trace formula on Heisenberg groups, which, together with the use of double operator integrals, allows us to bypass the use of Fourier analysis and provides a solid foundation to investigate the singular values estimates for similar commutators in general stratified Lie groups.

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