We explore the experimental sensitivities of measuring the $gg \rightarrow Z \gamma$ process at the LHC to the dimension-8 quartic couplings of gluon pairs to the boson and photon, in addition to comparing them with the analogous sensitivities in the process. These processes can both receive contributions from 4 different CP-conserving dimension-8 operators with distinct Lorentz structures that contain a pair of gluon field strengths, $\hat G^a_{\mu \nu}W^i_{\mu \nu}\hat G^a_{\mu \nu}B_{\mu \nu}$. We calculate the scattering angular distributions for and the decay angular distributions for these 4 Lorentz structures, as well as the Standard Model background. We analyze the sensitivity of ATLAS measurements of the $Z(\to \ell^+\ell^-, \bar \nu \nu, \bar q q)\gamma^{-1}\sqrt{s} = 13\lesssim 2$ TeV for the dimension-8 operator scales, and compare the sensitivity with that of an ATLAS measurement of the final state. We present combined and constraints on the scales of dimension-8 SMEFT operators and constraints on the nonlinearity scale of the Born-Infeld extension of the Standard Model. We also estimate the sensitivities to dimension-8 operators of experiments at possible future proton-proton colliders with centre-of-mass energies of 25, 50 and 100 TeV, and discuss possible measurements of the spin and angular correlations.

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