The degree of spin-orbit alignment in a population of binary stars can be determined from measurements of their orbital inclinations and rotational broadening of their spectral lines. Alignment in a face-on binary guarantees low rotational broadening, while alignment in an edge-on binary maximizes the rotational broadening. In contrast, if spin-orbit angles () are random, rotational broadening should not depend on orbital inclination. Using this technique, we investigated a sample of 2{,}727 astrometric binaries from Gaia DR3 with F-type primaries and orbital periods between 50 and 1000 days (separations 0.3–2.7~au). We found that is strongly associated with , the orbital eccentricity. When , the mean spin-orbit angle is ,degrees, while for , it rises to ,degrees. These results suggest that some binaries are affected by processes during their formation or evolution that excite both orbital eccentricity and inclination.

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