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We present a selection of results from our recent study of $pp\to t\bar{t}W^\pm$ production matched to partons showers at NLO QCD at the LHC. Theoretical predictions are obtained at perturbative orders and , where the different contributions are studied first separately at the inclusive level before being combined within a realistic two same-sign lepton signature. We investigate in detail uncertainties originating from missing higher-order corrections and from the parton-shower matching scheme employed.

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