In this paper we focus on three mass regions where first-order phase transitions occur, namely for , 60 and 90. We investigate four isotopic chains (Se, Zr, Mo and Nd) in the framework of microscopic Skyrme-Hartree-Fock + Bardeen-Cooper-Schrieffer calculations for 15 different parametrizations. The microscopic calculations show the typical behavior expected for first-order phase transitions. To find the best candidate for the critical point phase transition we propose new microscopic position and occupation indices calculated for positive-parity and negative-parity proton and neutron single-quasiparticle states around the Fermi level. The microscopic calculations are completed by macroscopic calculations within the Algebraic Collective Model (ACM), and compared to the experimental data for Se, Mo and Nd, considered to be the best candidates for the critical point nuclei.

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