High-quality single crystals of CoTiO are grown and used to elucidate in detail structural and magnetostructural effects by means of high-resolution capacitance dilatometry studies in fields up to 15 T which are complemented by specific heat and magnetization measurements. In addition, we refine the single-crystal structure of the ilmenite () phase. At the antiferromagnetic ordering temperature , pronounced -shaped anomaly in the thermal expansion coefficients signals shrinking of both the and axes, indicating strong magnetoelastic coupling with uniaxial pressure along yielding six times larger effect on than the pressure applied in-plane. The hydrostatic pressure dependency derived by means of Gr"uneisen analysis amounts to $\partial T_/ \partial p\approx 2.7(4)$~K/GPa. The high-field magnetization studies in static and pulsed magnetic fields up to 60~T along with high-field thermal expansion measurements facilitate in constructing the complete anisotropic magnetic phase diagram of CoTiO. While the results confirm the presence of significant magnetodielectric coupling, our data show that magnetism drives the observed structural, dielectric, and magnetic changes both in the short-range ordered regime well-above as well as in the long-range magnetically ordered phase.

生成讲解博客的中文版本

生成AI智能校验的中文版本