Association schemes on triples (ASTs) are ternary analogues of classical association schemes. Analogous to Schurian association schemes, ASTs arise from the actions of two-transitive groups. In this paper, we obtain the sizes and third valencies of the ASTs obtained from the two-transitive permutation groups by determining the orbits of the groups’ two-point stabilizers. Specifically, we obtain these parameters for the ASTs obtained from the actions of and , , , and , and , some subgroups of , some subgroups of $P\Gamma L(k,n)$, and the sporadic two-transitive groups. Further, we obtain the intersection numbers for the ASTs obtained from these subgroups of $P\Gamma L(k,n)A \Gamma L(k,n)$, and the sporadic two-transitive groups. In particular, the ASTs from these projective and sporadic groups are commutative.

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