We present expressions for the matrix elements of the spin–spin operator in a variety of coupling schemes. These results are then applied to calculate the expectation value $\langle\vec S_{\rm n}\cdot\vec S_{\rm p}\rangle$ in eigenstates of a schematic Hamiltonian describing neutrons and protons interacting in a single- shell through a Surface Delta Interaction. The model allows us to trace $\langle\vec S_{\rm n}\cdot\vec S_{\rm p}\rangle$ as a function of the competition between the isovector and isoscalar interaction strengths and the spin–orbit splitting of the shells. We find negative $\langle\vec S_{\rm n}\cdot\vec S_{\rm p}\rangleN=Z$ nuclei, contrary to what has been observed in hadronic inelastic scattering at medium energies. We discuss the possible origin of this discrepancy and indicate directions for future theoretical and experimental studies related to neutron–proton spin–spin correlations.

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