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We derive new integral estimates on substatic manifolds with boundary of horizon type, naturally arising in General Relativity. In particular, we generalize to this setting an identity due to Magnanini-Poggesi leading to the Alexandrov Theorem in the Euclidean space and improve on a Heintze-Karcher type inequality due to Li-Xia. Our method relies on the introduction of a new vector field with nonnegative divergence, generalizing to this setting the P-function technique of Weinberger.

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