In this paper, we mainly investigate the Cauchy problem of the non-viscous MHD equations with magnetic diffusion. We first establish the local well-posedness (existence,~uniqueness and continuous dependence) with initial data in critical Besov spaces with $1\leq p\leq\inftyT$ of the solution which depends on the norm of the Littlewood-Paley decomposition of the initial data. Then, we prove the global existence in critical Besov spaces. In particular, the results of global existence also hold in Sobolev space $ C([0,\infty); {H}^{s}(^2))\times \Big(C([0,\infty);{H}^{s-1}(^2))\cap L^2\big([0,\infty);{H}^{s}(^2)\big)\Big)s>2$, when the initial data satisfies and $|u_0|{B^1{\infty,1}(^2)}+|b_0|{{B}^{0}{\infty,1}(^2)}\leq \epsilon$. It’s worth noting that our results imply some large and low regularity initial data for the global existence, which improves considerably the recent results in \cite{weishen}.

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