In this paper we study the Hartree-Fock type system as follows: \begin{equation*} \left{ \begin{array}{ll} -Δu+V\left( x\right) u+ρ\left( x\right) φ_{ρ,\left(u,v\right) }u=\left\vert u\right\vert ^{p-2}u+β\left\vert v\right\vert^{\frac{p}{2}}\left\vert u\right\vert ^{\frac{p}{2}-2}u & ^{3}, \ -Δv+V\left( x\right) v+ρ\left( x\right) φ_{ρ,\left( u,v\right) }v=\left\vert v\right\vert ^{p-2}v+β\left\vert u\right\vert ^{\frac{p}{2}}\left\vert v\right\vert ^{\frac{p}{2}-2}v & ^{3}, \end{array} \right. \end{equation*} where the potentials are positive continuous functions in the parameter and . Such system is viewed as an approximation of the Coulomb system with two particles appeared in quantum mechanics, whose main characteristic is the presence of the double coupled terms. When under suitable assumptions on potentials, we shed some light on the behavior of the corresponding energy functional on and prove the existence of a global minimizer with negative energy. When we find vectorial ground states by developing a new analytic method and exploring the conditions on potentials. Finally, we study the phenomenon of symmetry breaking of ground states when

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