The generalized state space of all unital completely positive (UCP) maps on a unital -algebra taking values in the algebra of all bounded operators on a Hilbert space , is a -convex set. In this paper, we establish a connection between -extreme points of and a factorization property of certain algebras associated to the UCP map. In particular, this factorization property of some nest algebras is used to give a complete characterization of those -extreme maps which are direct sums of pure UCP maps. This significantly extends a result of Farenick and Zhou [Proc. Amer. Math. Soc. 126 (1998)] from finite to infinite dimensional Hilbert spaces. Also it is shown that normal -extreme maps on type factors are direct sums of normal pure UCP maps if and only if an associated algebra is reflexive. Further, a Krein-Milman type theorem is established for -convexity of the set equipped with bounded weak topology, whenever is a separable -algebra or it is a type factor. As an application, we provide a new proof of a classical factorization result on operator valued Hardy algebras.

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