This paper is concerned with the existence of ground states for a class of Kirchhoff type equation with combined power nonlinearities \begin{equation*} -\left(a+b\int_{^{3}}|\nabla u(x)|^{2}\right) \Delta u =\lambda u+|u|^{p-2}u+u^{5}\quad \ \ \lambda\in,\quad x\in^{3}, \end{equation*} with prescribed -norm mass \begin{equation*} \int_{^{3}}u^{2}=c^{2} \end{equation*} in Sobolev critical case and proves that the equation has a couple of solutions $(u_{c},\lambda_{c})\in S©\times c>0a,b >0\frac{14}{3}\leq p< 6,S©={u\in H^{1}(^{3}):\int_{^{3}}u^{2}=c^{2}}.$ Kirchhoff type equation; Critical nonlinearity; Normalized ground states \noindent{AMS Subject Classification:, 37L05; 35B40; 35B41.}

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