We present an analysis of the most massive white dwarf candidates in the
Montreal White Dwarf Database 100 pc sample. We identify 25 objects that would
be more massive than if they had pure H atmospheres and CO
cores, including two outliers with unusually high photometric mass estimates
near the Chandrasekhar limit. We provide follow-up spectroscopy of these two
white dwarfs and show that they are indeed significantly below this limit. We
expand our model calculations for CO core white dwarfs up to $M=1.334
M_\odot$, which corresponds to the high-density limit of our equation-of-state
tables, g cm. We find many objects close to this maximum
mass of our CO core models. A significant fraction of ultramassive white dwarfs
are predicted to form through binary mergers. Merger populations can reveal
themselves through their kinematics, magnetism, or rapid rotation rates. We
identify four outliers in transverse velocity, four likely magnetic white
dwarfs (one of which is also an outlier in transverse velocity), and one with
rapid rotation, indicating that at least 8 of the 25 ultramassive white dwarfs
in our sample are likely merger products.

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