Two-dimensional electrides can acquire topologically non-trivial phases due to intriguing interplay between the cationic atomic layers and anionic electron layers. However, experimental evidence of topological surface states has yet to be verified. Here, via angle-resolved photoemission spectroscopy (ARPES) and scanning tunnelling microscopy (STM), we probe the magnetic Weyl states of the ferromagnetic electride [Gd2C]^{2+}\cdot2e^{-}.Inparticular,thepresenceofWeylconesandFermi−arcstatesisdemonstratedthroughphotonenergy−dependentARPESmeasurements,agreeingwiththeoreticalbandstructurecalculations.Notably,theSTMmeasurementsrevealthattheFermi−arcstatesexistunderneathafloatingquantumelectronliquidonthetopGdlayer,formingdouble−stackedsurfacestatesinaheterostructure.Ourworkthusnotonlyunveilsthenon−trivialtopologyofthe[Gd_{2}C]2+⋅2e− electride but also realizes a surface heterostructure that can host phenomena distinct from the bulk.