The cosmic expansion rate can be directly measured with gravitational-wave (GW) data of the compact binary mergers by jointly constraining the mass function of the population and the cosmological model via the so-called spectral sirens. Such a method relies on the features in the mass functions, which may originate from some individual subpopulations, and hence become blurred/indistinct due to the superposition of different subpopulations. In this work we propose a novel approach to constrain the cosmic expansion rate with subpopulations of GW events, named multi-spectral sirens. The advantage of the multi-spectral sirens compared to the traditional spectral sirens is demonstrated by the simulation with the mock data. The application of this approach to the GWTC-3 data yields (median and symmetric 68.3% credible interval), which is about 19% tighter than the result inferred with the traditional spectral sirens utilizing a PowerLaw+Peak mass function. The incorporation of the bright standard siren GW170817 with a uniform prior in [10,200] (log-uniform prior in [20,140]) gives (68.3% confidence level), corresponding to an improvement of (23%) with respect to the measurement from sole GW170817.

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