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In this paper, we prove that associated with a sub-static asymptotically flat manifold endowed with a harmonic potential there is a one-parameter family of functions which are monotone along the level-set flow of the potential. Such monotonicity holds up to the optimal threshold and allows us to prove a geometric capacitary inequality where the capacity of the horizon plays the same role as the ADM mass in the celebrated Riemannian Penrose Inequality.

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