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Let be a Schr"odinger operator, where the potential belongs to the reverse H"older class. By the subordinative formula, we introduce the fractional heat semigroup , associated with . By the aid of the fundamental solution of the heat equation: we estimate the gradient and the time-fractional derivatives of the fractional heat kernel , respectively. This method is independent of the Fourier transform, and can be applied to the second order differential operators whose heat kernels satisfying Gaussian upper bounds. As an application, we establish a Carleson measure characterization of the Campanato type space via .

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