The key to unraveling intriguing phenomena observed in various Kitaev materials lies in understanding the interplay of Kitaev () interaction and a symmetric off-diagonal interaction. To provide insight into the challenging problems, we study the quantum phase diagram of a bond-alternating spin- - - chain by density-matrix renormalization group method where and are the bond strengths of the odd and even bonds, respectively. The phase diagram is dominated by even-Haldane ($g_x > g_yg_x < g_y$) phases where the former is topologically trivial while the latter is a symmetry-protected topological phase. Near the antiferromagnetic Kitaev limit, there are two gapped and phases characterized by distinct nonlocal string correlators. In contrast, the isotropic ferromagnetic (FM) Kitaev point serves as a multicritical point where two topological phase transitions meet. The remaining part of the phase diagram contains three symmetry-breaking magnetic phases. One is a six-fold degenerate FM phase where all the spins are parallel to one of the , , and axes in a six-site spin rotated basis, while the other two have more complex spin structures with all the three spin components being finite. Existence of a rank-2 spin-nematic ordering in the latter is also discussed.

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