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Pt/Graphene and Pt/MnO2-Graphene catalysts have been prepared by microwave-assisted polyol process. Electrochemical results show that Pt/MnO2-Graphene has higher electrocatalytic activity and stability. Furthermore, carbon riveted Pt/MnO2-Graphene catalyst has been designed and synthesized on the basis of in situ carbonization of L-ascorbic acid. The stability for carbon riveted Pt/MnO2-catalyst is significantly enhanced.

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