In this paper, we consider the following nonlinear Schrödinger system: - u+P(x)u= + u, x ,\ - v+Q(x)v= + v, x , where are positive radial potentials,~, is a coupling constant. We constructed a new type of solutions which are different from the ones obtained in \cite{PW}. This new family of solutions to system have a more complex concentration structure and are centered at the points lying on the top and the bottom circles of a cylinder with height . Moreover, we examine the effect of nonlinear coupling on the solution structure. In the repulsive case, we construct an unbounded sequence of non-radial positive vector solutions of segregated type. In the attractive case, we construct an unbounded sequence of non-radial positive vector solutions of synchronized type. Moreover, we prove that there exist infinitely many sign-changing solutions whose energy can be arbitrarily large.

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