Using the spectral theory on the -spectrum it is possible to define the fractional powers of a large class of vector operators. This possibility leads to new fractional diffusion and evolution problems that are of particular interest for nonhomogeneous materials where the Fourier law is not simply the negative gradient operator but it is a nonconstant coefficients differential operator of the form where, can be either a bounded or an unbounded domain in whose boundary is considered suitably regular, is the closure of and , for are the imaginary units of the quaternions . The operators , for , are called the components of and , , $a_3: \bar{\Omega} \subset^3\to T$. In this paper we study the generation of the fractional powers of , denoted by for , when the operators , for do not commute among themselves. To define the fractional powers of we have to consider the weak formulation of a suitable boundary value problem associated with the pseudo -resolvent operator of . In this paper we consider two different boundary conditions. If is unbounded we consider Dirichlet boundary conditions. If is bounded we consider the natural Robin-type boundary conditions associated with the generation of the fractional powers of .

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