We present the merger rate density of Population (Pop.) III binary black holes (BHs) by means of a widely-used binary population synthesis code BSE with extensions to very massive and extreme metal-poor stars. We consider not only low-mass BHs (lBHs: ) but also high-mass BHs (hBHs: $130-200 M_\odot$), where lBHs and hBHs are below and above the pair-instability mass gap (), respectively. Pop. III BH-BHs can be categorized into three subpopulations: BH-BHs without hBHs (hBH0s: $m_{\rm tot} \lesssim 100 M_\odotm_{\rm tot} \sim 130-260 M_\odot$), and with two hBHs (hBH2s: ), where is the total mass of a BH-BH. Their merger rate densities at the current universe are yr Gpc for hBH0s, and yr Gpc for the sum of hBH1s and hBH2s, provided that the mass density of Pop. III stars is Gpc. These rates are modestly insensitive to initial conditions and single star models. The hBH1 and hBH2 mergers can dominate BH-BHs with hBHs discovered in near future. They have low effective spins in the current universe. The number ratio of the hBH2s to the hBH1s is high, . We also find BHs in the mass gap (up to ) merge. These merger rates can be reduced to nearly zero if Pop. III binaries are always wide (), and if Pop. III stars always enter into chemically homogeneous evolution. The presence of close Pop. III binaries () are crucial for avoiding the worst scenario.

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