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In this paper, we consider the following singularly perturbed Kirchhoff equation \begin{equation*} -(\varepsilon^2a+\varepsilon b\int_{^3}|\nabla u|^2dx)\Delta u+V(x)u=P(x)|u|^{p-2}u+Q(x)|u|^4u,\quad x\in^3, \end{equation*} where is a small parameter, are constants, and are potential functions satisfying some competing conditions. We prove the existence of a positive ground state solution by using variational methods, and we determine a concrete set related to the potentials and as the concentration position of these ground state solutions as .

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