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In the present paper we study SKT and generalized Kähler structures on solvable Lie algebras with (not necessarily abelian) codimension two nilradical. We treat separately the case of -invariant nilradical and non -invariant nilradical. A classification of such SKT Lie algebras in dimension six is provided. In particular, we give a general construction to extend SKT nilpotent Lie algebras to SKT solvable Lie algebras of higher dimension, and we construct new examples of SKT and generalized Kähler compact solvmanifolds.

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