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A classical construction associates to a transient random walk on a discrete group a compact -space known as the Martin boundary. The resulting crossed product -algebra $C(\partial_M \Gamma) \rtimes_r \Gamma$ comes equipped with a one-parameter group of automorphisms given by the Martin kernels that define the Martin boundary. In this paper we study the KMS states for this flow and obtain a complete description when the Poisson boundary of the random walk is trivial and when is a torsion free non-elementary hyperbolic group. We also construct examples to show that the structure of the KMS states can be more complicated beyond these cases.

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