We investigate the superheating fields of semi-infinite superconductors and layered superconductors in the diffusive limit by using the well-established quasiclassical Green’s function formalism of the BCS theory. The coupled Maxwell-Usadel equations are self-consistently solved to obtain the spatial distributions of the magnetic field, screening current density, penetration depth, and pair potential. We find the superheating field of a semi-infinite superconductor in the diffusive limit is given by $H_{sh} = 0.795 H_{c0}T \to 0H_{c0}$ is the thermodynamic critical-field at the zero temperature. Also, we evaluate of layered superconductors in the diffusive limit as functions of the layer thicknesses () and identify the optimum thickness that maximizes for various materials combinations. Qualitative interpretation of based on the London approximation is also discussed. The results of this work can be used to improve the performance of superconducting rf resonant cavities for particle accelerators.

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