We examine the polarized doubly-virtual Compton scattering (VVCS) off the nucleon using chiral perturbation theory (PT). The polarized VVCS contains a wealth of information on the spin structure of the nucleon which is relevant to the calculation of the two-photon-exchange effects in atomic spectroscopy and electron scattering. We report on a complete next-to-leading-order (NLO) calculation of the polarized VVCS amplitudes and , and the corresponding polarized spin structure functions and . Our results for the moments of polarized structure functions, partially related to different spin polarizabilities, are compared to other theoretical predictions and “data-driven” evaluations, as well as to the recent Jefferson Lab measurements. By expanding the results in powers of the inverse nucleon mass, we reproduce the known “heavy-baryon” expressions. This serves as a check of our calculation, as well as demonstrates the differences between the manifestly Lorentz-invariant baryon PT (BPT) and heavy-baryon (HBPT) frameworks.

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