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For a domain in a geodesically convex surface, we introduce a scattering energy , which measures the asymmetry of by quantifying its incompatibility with an isometric circle action. We prove several sharp quantitative isoperimetric inequalities involving and characterize the domains with vanishing scattering energy by their convexity and rotational symmetry. We also give a new proof of the sharp Sobolev inequality for Riemannian surfaces which is independent of the isoperimetric inequality.

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