Quantization of the charge in Coulomb plus harmonic potential

We consider two models where the wave equation can be reduced to the effective Schr"odinger equation whose potential contains both harmonic and the Coulomb terms, ${\omega }^2{r}^2-a\mathrm{/}r$. The equation reduces to the biconfluent Heun’s equation, and we find that the charge as well as the energy must be quantized and state dependent. We also find that two quantum numbers are necessary to count radial degrees of freedom and suggest that this is a general feature of differential equation with higher singularity like the Heun’s equation.