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An asymptotic expression of the orthonormal polynomials as , associated with the singularly perturbed Laguerre weight $w_{\alpha}(x;t)=x^{\alpha}{\rm e}^{-x-\frac{t}{x}},~x\in[0,\infty),~\alpha>-1,~t\geq0$ is derived. Based on this, we establish the asymptotic behavior of the smallest eigenvalue, , of the Hankel matrix generated by the weight .

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