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We study the five-quark system composed of configuration ($q = udQ=bc$), in the framework of the chiral quark model. In consequence, a series of bound states with heavy flavors are predicted by precise five-body dynamical calculations. We found that taking color-octet structure into consideration always provides more bounding energy than color-singlet structure, and the more heavier quark prevents, the easier to form the bound states. We suggest configuration is a compact -pair surrounded by three other quarks, while , and configurations are molecular states.

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