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We present a new experimental method for measuring inner-shell ionization cross sections of low-charged ions colliding with hydrogen gas target in a storage ring. The method is based on a calibration by the well-known differential cross sections of proton elastic scattering on nuclei. -shell ionization cross section of 1047(100) barn for the 95 MeV/u Ni ions colliding with hydrogen atoms was obtained in this work. Compared to the measured ionization cross section, a good agreement is achieved with the prediction by the Relativistic Ionization CODE Modified program (RICODE-M).

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