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We report on a search for elementary particles with charges much smaller than the electron charge using a data sample of proton-proton collisions provided by the CERN Large Hadron Collider in 2018, corresponding to an integrated luminosity of 37.5 fb at a center-of-mass energy of 13 TeV. A prototype scintillator-based detector is deployed to conduct the first search at a hadron collider sensitive to particles with charges . The existence of new particles with masses between 20 and 4700 MeV is excluded at 95% confidence level for charges between and , depending on their mass. New sensitivity is achieved for masses larger than MeV.

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