We propose a new approach to probe the spatial extension of the valence neutron orbital in the Be nucleus via the Be()Be knockout reaction. This property of the nuclear molecular orbital has not been established in previous experimental studies and divergence exists between the theoretical descriptions of Be from different perspectives, , the antisymmetrized molecular dynamics and the container pictures of cluster dynamics. These pictures are represented by two different well-proven microscopic models, the antisymmetrized molecular dynamics (AMD) and Tohsaki-Horiuchi-Schuck-R"{o}pke (THSR) wave functions. The corresponding reduced width amplitudes (RWAs) in the Be channel are extracted from both the AMD and THSR wave functions, and they are found to describe drastically different valence-nucleon motion, which shows the theoretical ambiguity in describing the -orbitals in Be. Using the RWAs as input, the physical observables of the Be()Be knockout reaction are predicted by the distorted-wave impulse approximation (DWIA) framework. The magnitudes of the triple-differential cross sections (TDX) are found to be highly sensitive to the RWA input. It is concluded that the Be()Be knockout reaction could provide a feasible probing for the subtle differences between several structure models manifesting through the spatial extension of the -orbital in the Be nucleus.

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