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We identify a new mechanism for the intrinsic superconducting diode effect (SDE) in multiphase superconductors. Using a Ginzburg-Landau and a microscopic two-band model, we find phase transitions into a mixed phase with finite-momentum Cooper pairs and SDE with high (including maximal) diode efficiencies, despite the individual phases exhibiting no SDE and equal inversion parity. We thus show that parity mixing invoked in previous proposals is not a crucial ingredient for SDE. The new mechanism may be relevant in a multitude of known multiphase superconductors like UTe.

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