Following the work of Burger, Iozzi and Wienhard for representations, in this paper we introduce the notion of maximal measurable cocycles of a surface group. More precisely, let be a semisimple algebraic -group such that is of Hermitian type. If is a torsion-free lattice of a finite connected covering of , given a standard Borel probability -space , we introduce the notion of Toledo invariant for a measurable cocycle . The Toledo remains unchanged along -cohomology classes and its absolute value is bounded by the rank of . This allows to define maximal measurable cocycles. We show that the algebraic hull of a maximal cocycle is reductive and the centralizer of is compact. If additionally admits a boundary map, then is of tube type and is cohomologous to a cocycle stabilizing a unique maximal tube-type subdomain. This result is analogous to the one obtained for representations. In the particular case maximality is sufficient to prove that is cohomologous to a cocycle preserving a complex geodesic. We conclude with some remarks about boundary maps of maximal Zariski dense cocycles.

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