For an acyclic quiver, we establish a connection between the cohomology of quiver Grassmannians and the dual canonical bases of the algebra , where is the negative half of the quantized enveloping algebra associated with the quiver. In order to achieve this goal, we study the cohomology of quiver Grassmannians by Lusztig’s category. As a consequence, we describe explicitly the Poincar'e polynomials of rigid quiver Grassmannians in terms of the coefficients of dual canonical bases, which are viewed as elements of quantum shuffle algebras. By this result, we give another proof of the odd cohomology vanishing theorem for quiver Grassmanians. Meanwhile, for Dynkin quivers, we show that the Poincar'e polynomials of rigid quiver Grassmannians are the coefficients of dual PBW bases of the algebra .

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