We revisit critical behaviour and phase structure of charged anti-deSitter (AdS) dilaton black holes for arbitrary values of dilaton coupling , and realize several novel phase behaviour for this system. We adopt the viewpoint that cosmological constant (pressure) is fixed and treat the charge of the black hole as a thermodynamical variable. We study critical behaviour and phase structure by analyzing the phase diagrams in and planes. We numerically derive the critical point in terms of and observe that for and , the system does not admit any critical point, while for , the critical quantities are not significantly affected by . We find that unstable behavior of the Gibbs free energy for exhibits a (discontinuous) phase transition between small and large black holes for . For and , however, a novel first order phase transition occurs between small and large black hole, which has not been observed in the previous studies on phase transition of charged AdS black holes.

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