We study the Sobolev spaces and on p.c.f. self-similar sets in terms of the boundary behavior of functions. First, for , we make an exact description of the tangents of functions in at the boundary. Second, we characterize as the space of functions in with zero tangent of an appropriate order depending on . Last, we extend to , and obtain various interpolation theorems with or . We illustrate that there is a countable set of critical orders, that arises naturally in the boundary behavior of functions, such that presents a critical phenomenon if is critical. These orders will play a crucial role in our study. They are just the values in in the classical case, but are much more complicated in the fractal case.

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