We study pseudospectral and spectral functions for Hamiltonian system and differential equation with matrix-valued coefficients defined on an interval with the regular endpoint . It is not assumed that the matrix weight is invertible a.e. on . In this case a pseudospectral function always exists, but the set of spectral functions may be empty. We obtain a parametrization of all pseudospectral and spectral functions by means of a Nevanlinna parameter and single out in terms of and boundary conditions the class of functions for which the inverse Fourier transform $y(t)=\int\limits_{} \varphi(t,s), d\sigma (s) \widehat y(s)$ converges uniformly. We also show that for scalar equation the set of spectral functions is not empty. This enables us to extend the Kats-Krein and Atkinson results for scalar Sturm - Liouville equation $-(p(t)y’)'+q(t)y=\lambda \Delta (t) yp(t)q(t)$ and arbitrary non trivial weight .

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