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In this paper, we introduce notions of (proto-, quasi-)twilled Lie triple systems and give their equivalent descriptions using the controlling algebra and bidegree convention. Then we construct an -algebra via a twilled Lie triple system. Besides, we establish the twisting theory of Lie triple systems and then characterize the twisting as a Maurer-Cartan element in the constructed -algebra. Finally, we clarify the relationship between twilled Lie triple systems and matched pairs and clarify the relationship between twilled Lie triple systems and relative Rota-Baxter operators respectively so that we obtain the relationship between matched pairs of Lie triple systems and relative Rota-Baxter operators.

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