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For a non-compact simple Lie algebra over , we denote by the unique complex nilpotent orbit in containing all minimal real nilpotent orbits in . In this paper, we give a complete classification of symmetric pairs such that , where denotes the dual Lie algebra of . Furthermore, for symmetric pairs with real simple Lie group , we apply our classification to theorems given by T. Kobayashi [J. Lie Theory (2023)], and study bounded multiplicity properties of restrictions on of infinite-dimensional irreducible -representations with minimum Gelfand–Kirillov dimension.

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