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Let be a valued field. We review some results of MacLane and Vaqui'e on extensions of to valuations on the polynomial ring . We introduce certain MacLane-Vaqui'e chains of residually transcendental valuations, and we prove that every valuation on is a limit of a finite or countably infinite MacLane-Vaqui'e chain. This chain underlying is essentially unique and contains arithmetic data yielding an explicit description of the graded algebra of as an algebra over the graded algebra of .

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